(E)-3-(3,4-Dimethoxy­phen­yl)-1-(2-fur­yl)prop-2-en-1-one

نویسندگان

  • Hoong-Kun Fun
  • P. S. Patil
  • Samuel Robinson Jebas
  • S. M. Dharmaprakash
چکیده

In the title mol-ecule, C(15)H(14)O(4), the benzene and furyl rings are inclined to each other with a dihedral angle of 41.5 (1)°. An intra-molecular C-H⋯O hydrogen-bond inter-action generates an S(5) ring motif. In the crystal structure, mol-ecules are stacked along the b axis and the crystal packing is stabilized by inter-molecular C-H⋯O and C-H⋯π inter-actions. In addition, π-π stacking inter-actions with a centroid-to-centroid distance of 3.5855 (11) Å are observed.

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منابع مشابه

(E)-3-(3,4-Dimethoxy­phen­yl)-1-(2-thien­yl)prop-2-en-1-one

The title compound, C(15)H(14)O(3)S, has two symmetry-independent mol-ecules in the asymmetric unit with almost identical geometry. The dihedral angle between the benzene and thio-phene rings is 1.61 (11)° in one mol-ecule and 7.21 (11)° in the other. In both mol-ecules, C-H⋯O hydrogen bonds generate rings of graph-set motif S(5). The crystal structure is stabilized by C-H⋯O hydrogen bonds, C-H...

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Crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one

The crystal structures of three chalcones with a bromo-substituted but-oxy side chain, viz. (E)-1-[4-(4-bromo-but-oxy)-phen-yl]-3-phenyl-prop-2-en-1-one, C19H19BrO2, (I), (E)-1-[4-(4-bromo-but-oxy)-phen-yl]-3-(4-meth-oxy-phen-yl)prop-2-en-1-one, C20H21BrO3, (II), and (E)-1-[4-(4-bromo-but-oxy)-phen-yl]-3-(3,4-di-meth-oxy-phen-yl)prop-2-en-1-one, C21H23BrO4, (III), are reported. In all mol-ecule...

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(E)-1-(4-Bromo­phen­yl)-3-(2-fur­yl)prop-2-en-1-one

In the title compound, C(13)H(9)BrO(2), the benzene and furan rings form a dihedral angle of 44.35 (14)°. The crystal packing exhibits no significantly short inter-molecular contacts.

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1-(4-Chloro­phen­yl)-3-(5-methyl-2-fur­yl)prop-2-en-1-one

The title compound, C(14)H(11)ClO(2), was prepared from 4-chloro-hypnone and 5-methyl-furfural by an aldol condensation reaction. The dihedral angle formed between the two benzene rings is 7.71 (2)°. The crystal structure is stabilized by C-H⋯O inter-actions.

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(E)-3-(2-Fur­yl)-1-(2-hydroxy­phen­yl)prop-2-en-1-one

In the title mol-ecule, C(13)H(10)O(3), an intra-molecular O-H⋯O hydrogen bond influences the mol-ecular conformation, and the benzene and furan rings form a dihedral angle of 8.35 (7)°. Weak inter-molecular C-H⋯O hydrogen bonds link mol-ecules into sheets parallel to the bc plane.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008